pH, pOH, H, OH Relationships:
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This calculator determines the relationships between pH, pOH, hydrogen ion concentration [H⁺], and hydroxide ion concentration [OH⁻] in aqueous solutions. These parameters are fundamental to understanding acid-base chemistry.
The calculator uses the following mathematical relationships:
Where:
Explanation: These equations are derived from the ion product of water (K_w = 1.0 × 10⁻¹⁴ at 25°C) and the definition of pH and pOH scales.
Details: Accurate calculation of these parameters is essential for chemical analysis, water treatment, biological systems, industrial processes, and environmental monitoring.
Tips: Enter any one known value (pH, pOH, [H⁺], or [OH⁻]) and the calculator will compute the other three values. Values must be within valid ranges (pH/pOH: 0-14, concentrations: 1e-14 to 1 mol/L).
Q1: What is the relationship between pH and pOH?
A: pH + pOH = 14 at 25°C. This relationship comes from the ion product of water where [H⁺][OH⁻] = 1.0 × 10⁻¹⁴.
Q2: What are typical pH values for common substances?
A: Battery acid: ~0, Lemon juice: ~2, Pure water: 7, Sea water: ~8, Bleach: ~13.
Q3: How does temperature affect these calculations?
A: The ion product of water changes with temperature, so the relationship pH + pOH = pK_w varies slightly from 14 at different temperatures.
Q4: What is the significance of logarithmic scales?
A: pH and pOH use logarithmic scales to conveniently represent the wide range of hydrogen and hydroxide ion concentrations (from 1 to 10⁻¹⁴ mol/L).
Q5: Can this calculator be used for concentrated solutions?
A: For highly concentrated solutions (>1M), activity coefficients should be considered as the simple relationships may not hold accurately.